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The mechanism difference matters: hydroquinone works by denaturing tyrosinase on contact, while glutathione depletes the copper cofactor that tyrosinase requires to catalyse melanin synthesis

N-acetyl cysteine functions as a fast-acting antioxidant by triggering intracellular H 2 S and sulfane sulfur production

NAD also regulates enzymes involved in DNA repair, metabolic signaling, and mitochondrial health

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These effects generally indicate either starting doses too high or individual sensitivity