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This review aims to briefly discuss the endogenous sources (e.g., mitochondria, NADPH, and xanthine oxidase), and exogenous sources (e.g., smoking and radiation) of ROS (e.g., superoxide radical, hydrogen peroxide, and peroxynitrite)

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Tryptophan oxidation is the most common degradation route detected by RP-HPLC in stored melanocortin analogues, with histidine a secondary site of concern, and freeze-thaw cycling accelerates both aggregation and oxidative degradation