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They proposed that this L-KYN might prompt NK cells to move towards ferroptosis, but the key lies in avoiding the aromatic hydrocarbon receptor (AHR) pathway

In addition to the major ROS processing enzymes, in testis small molecular weight antioxidant substances are present, protecting against oxidative damage

So I wouldnt say that its necessarily better to get the vitamin D from the sun than from a vitamin D supplement or from eating fish or from eating cod liver oil