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Temperature fluctuations, repeated freeze-thaw cycles, prolonged room-temperature exposure, and excessive light can all reduce peptide stability over time

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However, supplements don't seem to help

Nutr Metab Cardiovasc Dis 19:291302

Eur J Pharm Sci 203:106939 Tian X, Zeng G, Li X, Wu Z, Wang L (2015) Cantharidin inhibits cell proliferation and promotes apoptosis in tongue squamous cell carcinoma through suppression of miR-214 and regulation of p53 and Bcl-2/Bax